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Acyclic stereocontrol via sequential and tandem [2,3]-Wittig-anionic oxy-Cope rearrangements

โœ Scribed by Nicholas Greeves; Katya Jane Vines

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
291 KB
Volume
35
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Stereoselective [2,3]-Wittig and Tandem
Stereoselective [2,3]-Wittig and Tandem [2,3]-Wittig-Anionic Oxy-Cope Rearrangements of Bis-allylic Ethers : Effect of Substituents
โœ Nicholas Greeves; Wai-Man Lee ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 589 KB

Acyclic bis-allylic ethers undergo,syn or anti stereoselective[2,3]-Wittig rearrangementto give homoallylic alcohols dependingon the substituents,and E-selective tandem [2,3]-Wittig-anionic oxy-Coperearrangementto give 8,&-unsaturated aldehydes. O 1997Elsevier ScienceLtd.