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Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement: a synthetic application of sequential [2,3]Wittig-oxy-Cope rearrangements

โœ Scribed by Wei, Shih Yi; Tomooka, Katsuhiko; Nakai, Takeshi


Book ID
126277018
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
285 KB
Volume
56
Category
Article
ISSN
0022-3263

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Stereoselective [2,3]-Wittig and Tandem
โœ Nicholas Greeves; Wai-Man Lee ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 589 KB

Acyclic bis-allylic ethers undergo,syn or anti stereoselective[2,3]-Wittig rearrangementto give homoallylic alcohols dependingon the substituents,and E-selective tandem [2,3]-Wittig-anionic oxy-Coperearrangementto give 8,&-unsaturated aldehydes. O 1997Elsevier ScienceLtd.