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ChemInform Abstract: Acetogenic Isoquinoline Alkaloids. Part 117. First Total Synthesis of Dioncophylline B, a 7,6′-Coupled Naphthylisoquinoline Alkaloid.

✍ Scribed by Gerhard Bringmann; Christian Guenther

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Acetogenic Isoquinoline Alkaloids. Part 117. First Total Synthesis of Dioncophylline B, a 7,6'-Coupled Naphthylisoquinoline Alkaloid.

-The title compound is synthesized by a crucial biaryl coupling of the appropriately functionalized naphthalene (I) and the isoquinoline (II) with Mom-protected oxygen substituents next to the coupling sites, thus providing the first example of the preparation of any 7,6'-coupled naphthylisoquinoline alkaloid.

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ChemInform Abstract: Acetogenic Isoquino
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