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ChemInform Abstract: A Very Short and Efficient Total Synthesis of Otanthus Maritima Amide.

โœ Scribed by M. BELLASSOUED; M. SALEMKOUR; E. REBOUL


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Very Short and Ef
โœ J. COSSY; S. BOUZBOUZ; A. HAKIKI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

The synthesis of the title compound (VI), a brasilane sesquiterpenoid alcohol, is achieved from the (R)-pulegone derivative (I) in only three steps. The key to success is the diastereoselective radical addition of the tertiary radical derived from (II) to the electrophilic radicophile (I). -(COSSY,