ChemInform Abstract: A Short and Efficient Synthesis of (.+-.) Laevigatin.
β Scribed by S. P. CHAVAN; Y. T. S. RAO; C. A. GOVANDE; P. K. ZUBAIDHA; V. D. DHONDGE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The synthesis of the title compound (VI), a brasilane sesquiterpenoid alcohol, is achieved from the (R)-pulegone derivative (I) in only three steps. The key to success is the diastereoselective radical addition of the tertiary radical derived from (II) to the electrophilic radicophile (I). -(COSSY,
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