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ChemInform Abstract: A Synthesis of (.+-.)-Stemodinone: An Application of Organoiron Chemistry to the Construction of Sterically Congested Quaternary Carbon Centers.

✍ Scribed by A. J. PEARSON; X. FANG

Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199752202

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✦ Synopsis

A Synthesis of (±)-Stemodinone: An Application of Organoiron Chemistry to the Construction of Sterically Congested Quaternary Carbon Centers.

-Iron complex (I) is used as starting A ring precursor in the construction of the stemodinone ring system. Coupling of complex (I) with enolstannane (II) that corresponds to the D ring and following elaboration of the remaining rings by appropriate bond connections between the residues incorporated into each subunit gives the enone ( XIV), that represents the direct precursor for the target stemodinone ( XV). -(PEARSON, A.

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