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ChemInform Abstract: Application of the Reetz Reagent, Dichlorodimethyltitanium, to Develop Sterically Congested Quaternary Centers. The Synthesis of Herbertene.

✍ Scribed by T. POON; B. P. MUNDY; F. G. FAVALORO; C. A. GOUDREAU; A. GREENBERG; R. SULLIVAN

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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A Synthesis of (Β±)-Stemodinone: An Application of Organoiron Chemistry to the Construction of Sterically Congested Quaternary Carbon Centers. -Iron complex (I) is used as starting A ring precursor in the construction of the stemodinone ring system. Coupling of complex (I) with enolstannane (II) tha