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ChemInform Abstract: A Strategy for the Synthesis of Popolohuanone E: Formal Total Synthesis of (.+-.)-Arenarol.

✍ Scribed by J. C. ANDERSON; D. J. PEARSON

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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ChemInform Abstract: Studies Toward the
ChemInform Abstract: Studies Toward the Synthesis of Popolohuanone E: Synthesis of Natural (+)-Arenarol Related to the Proposed Biogenetic Precursor of Popolohuanone E.
✍ H. KAWANO; M. ITOH; T. KATOH; S. TERASHIMA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB

The cis-fused decalin segment (VIII) is prepared starting from Wieland-Miescher ketone (I) via orthoester Claisen rearrangement and Ir-catalyzed specific hydrogenation. Coupling of (VIII) with arene (IX) gives rise to formation of the desired title compound (XI), contained twice in the target substa