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ChemInform Abstract: Studies Toward the Synthesis of Popolohuanone E: Synthesis of Natural (+)-Arenarol Related to the Proposed Biogenetic Precursor of Popolohuanone E.

✍ Scribed by H. KAWANO; M. ITOH; T. KATOH; S. TERASHIMA

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The cis-fused decalin segment (VIII) is prepared starting from Wieland-Miescher ketone (I) via orthoester Claisen rearrangement and Ir-catalyzed specific hydrogenation. Coupling of (VIII) with arene (IX) gives rise to formation of the desired title compound (XI), contained twice in the target substance popolohuanone E. -(KAWANO, H.; ITOH, M.; KATOH,

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