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ChemInform Abstract: A Steric Control of Regioselectivity in Palladium-Catalyzed Cyclizations of Alkenes Bearing Arylbromides and Nucleophiles.

✍ Scribed by D. BRUYERE; G. GAIGNARD; D. BOUYSSI; G. BALME; J.-M. LANCELIN

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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The stereocontrolled synthesis of tricyclic compounds through an efficient and highly regioselective 5-exo-trig palladium catalyzed biscyclization process is reported, starting from compounds 1. The 6-endo competing cyclization can also be the only pathway leading to transoctahydrophenanthrene. In t