ChemInform Abstract: Regioselectivity in the Palladium-Catalyzed Addition of Carbon Nucleophiles to Dihydropyran Derivatives.
β Scribed by M.-R. BRESCIA; Y. C. SHIMSHOCK; P. DESHONG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes. -A new, catalytic route to the synthesis of differently substituted allenes is developed by addition of cyano-based carbon nucleophiles to conjugated enynes. Pd2(dba)3β’CHCl3/dppf is found to be the best catalytic system fo
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