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ChemInform Abstract: A Simple Borohydride-Based Method for Selective 1,4-Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds.

✍ Scribed by Alyssa T. Russo; Kerstin L. Amezcua; Vincent A. Huynh; Zach M. Rousslang; David B. Cordes

Book ID
112042759
Publisher
John Wiley and Sons
Year
2012
Weight
35 KB
Volume
43
Category
Article
ISSN
0931-7597

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A simple procedure for selective reducti
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✍ Manoj J. Hazarika; Nabin C. Barua 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 187 KB

A combination of aluminium and nickel chloride in THF has been shown to effect the selective reduction of the olefinic double bond of the d-enone system. Isolated double bonds and aliphatic carbonyls remain unaffected under these conditions. However, aromatic aldehydes and ketones are converted to t