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A simple borohydride-based method for selective 1,4-conjugate reduction of α,β-unsaturated carbonyl compounds

✍ Scribed by Alyssa T. Russo; Kerstin L. Amezcua; Vincent A. Huynh; Zach M. Rousslang; David B. Cordes

Book ID
113930148
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
238 KB
Volume
52
Category
Article
ISSN
0040-4039

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A simple procedure for selective reducti
A simple procedure for selective reduction of α,β-unsaturated carbonyl compounds using Al-NiCl2 system
✍ Manoj J. Hazarika; Nabin C. Barua 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 187 KB

A combination of aluminium and nickel chloride in THF has been shown to effect the selective reduction of the olefinic double bond of the d-enone system. Isolated double bonds and aliphatic carbonyls remain unaffected under these conditions. However, aromatic aldehydes and ketones are converted to t