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ChemInform Abstract: A Short and Efficient Synthesis of the tRNA Nucleosides PreQ0 and Archaeosine.

✍ Scribed by Tobias Brueckl; Florian Klepper; Katrin Gutsmiedl; Thomas Carell


Publisher
John Wiley and Sons
Year
2008
Weight
20 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Very Short and Ef
✍ J. COSSY; S. BOUZBOUZ; A. HAKIKI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

The synthesis of the title compound (VI), a brasilane sesquiterpenoid alcohol, is achieved from the (R)-pulegone derivative (I) in only three steps. The key to success is the diastereoselective radical addition of the tertiary radical derived from (II) to the electrophilic radicophile (I). -(COSSY,