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ChemInform Abstract: A Novel Synthesis of Cadmium Phosphide Nanoparticles Using the Single-Source Precursor [MeCdPtBu2]3.

✍ Scribed by M. GREEN; P. O'BRIEN

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel Synthesis of Cadmium Phosphide Nanoparticles Using the Single-Source Precursor [MeCdP t Bu 2 ] 3 .

-Tri-n-octylphosphine oxide (TOPO) capped Cd 3 P 2 quatum dots are prepared by thermolysis of a TOPO/TOP solution of MeCdP(tBu) 2 at 90-250 β€’ C. The precursor is obtained in high purity by direct reaction of Me 2 Cd and tBu 2 HP in dry hexane or trioctylphosphine (TOP). The optical properties and the size of the cadmium phosphide nanocrystals depend on the thermolysis conditions . - (GREEN,

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