ChemInform Abstract: A Novel Method for Introducing a Polyfluoroalkyl Group into Aromatic Compounds.
โ Scribed by Ryuhei Tahara; Tadahito Fukuhara; Shoji Hara
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 42 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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Iodine monofluoride, generated from XeF 2 and I 2 or NIS, reacts with alkenes to furnish iodofluorinated products [cf. (II), (IV), (V)] in good yields. The reaction of aromatics with XeF 2 and I 2 or NIS proceeds as electrophilic aromatic iodination [โ (VII), (IX)]. Iodine monofluoride (IF), generat