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ChemInform Abstract: A Mild Method for Introducing Iodine Monofluoride into Alkenes and Iodination of Aromatics Using Xenon Difluoride.

✍ Scribed by D. F. SHELLHAMER; B. C. JONES; B. J. PETTUS; T. L. PETTUS; J. M. STRINGER; V. L. HEASLEY

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Iodine monofluoride, generated from XeF 2 and I 2 or NIS, reacts with alkenes to furnish iodofluorinated products [cf. (II), (IV), (V)] in good yields. The reaction of aromatics with XeF 2 and I 2 or NIS proceeds as electrophilic aromatic iodination [β†’ (VII), (IX)]. Iodine monofluoride (IF), generated from XeF 2 proves to be less reactive than IF generated from I 2 and fluorine gas.

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