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ChemInform Abstract: A Novel Hydride Rearrangement of the Acetal Group of Tetraacetal Tetraoxa-Cages Mediated by Lewis Acids.

โœ Scribed by H.-J. WU; J.-H. CHERN


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Alkylation of a
โœ M. Teresa Barros; Anthony J. Burke; Christopher D. Maycock ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

The Alkylation of a Novel Acetal Derived from (2R,3R)-(+)-Tartaric Acid: An Unexpected Rearrangement. -Unexpected base-induced rearrangement of the chiral bis-acetal (IV) gives optically active dioxolane (V) accompanied by the two dioxanes (VI) and (VII). The product distribution depends on the equ