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ChemInform Abstract: The Alkylation of a Novel Acetal Derived from (2R,3R)-(+)-Tartaric Acid: An Unexpected Rearrangement.

✍ Scribed by M. Teresa Barros; Anthony J. Burke; Christopher D. Maycock

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199918131

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✦ Synopsis

The Alkylation of a Novel Acetal Derived from (2R,3R)-(+)-Tartaric Acid: An Unexpected Rearrangement.

-Unexpected base-induced rearrangement of the chiral bis-acetal (IV) gives optically active dioxolane (V) accompanied by the two dioxanes (VI) and (VII). The product distribution depends on the equivalents of LDA used and the reaction time. -(BARROS,

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