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ChemInform Abstract: A New Approach to Densely Functionalized Azepines and Dihydroazepines.

โœ Scribed by Nina A. Nedolya; Ol'ga A. Tarasova; Alexander I. Albanov; Ol'ga G. Volostnykh; Lambert Brandsma; Boris A. Trofimov

Publisher
John Wiley and Sons
Year
2008
Weight
29 KB
Volume
39
Category
Article
ISSN
0931-7597

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The convergent approach to a broad variety of functionalized alkynes starts with a Knoevenagel-type condensation of 4-unsubstituted isoxazolines with ketones or aldehydes. The resulting adducts are subjected to Michael addition with various nucleophiles such as hydride, cyanide or phosphite. Exposur