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ChemInform Abstract: Rearrangement of 3,5-Dicyano-1,4-dihydropyridines to Densely Functionalized Cyclopentadienes.

โœ Scribed by Stefania Fusi; Fabio Ponticelli; Antonio Ventura; Mauro F. A. Adamo

Publisher
John Wiley and Sons
Year
2009
Weight
26 KB
Volume
40
Category
Article
ISSN
0931-7597

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Synthesis of N-Methylmorpholinium 6-Amino-4-aryl-4-methyl-3,5dicyano-1,4-dihydropyridine-2-thiolates under Conditions of Michael Reaction. -Reaction of alkylidenemalononitriles (I) with cyanothioacetamide (II) affords the corresponding Michael adducts which cyclize immediately to the title 1,4-dihy