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ChemInform Abstract: A General Route to 4-C-Branched Sugars. Synthesis of Methyl α-Caryophylloside.

✍ Scribed by Jacques Prandi


Publisher
John Wiley and Sons
Year
2001
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis and Relat
✍ J. LONGEPE; J. PRANDI; J.-M. BEAU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

Synthesis and Relative Configuration of a C-4 Branched Sugar, a Component of the Lipooligosaccharide LOS-III from Mycobacterium gastri. -For a general route to C-4 branched sugars, a connection between C-4 and C-7 is necessary. This bond formation is achieved by a SmI2 promoted coupling of the keto