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ChemInform Abstract: A Formal Total Synthesis of Epothilone A: Enantioselective Preparation of the C1—C6 and C7—C12 Fragments

✍ Scribed by Richard E. Taylor; Gabriel M. Galvin; Kerry A. Hilfiker; Yue Chen

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis Studies D
ChemInform Abstract: Synthesis Studies Directed Towards Epothilone A: Enantioselective Synthesis of a C7—C15 Carboxaldehyde Segment.
✍ P. BIJOY; M. A. AVERY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Synthesis Studies Directed Towards Epothilone A: Enantioselective Synthesis of a C 7 -C 15 Carboxaldehyde Segment. -Based on the diastereoselective alkylation of Oppolzer's sultam (III) with the iodide (II), the desired (S)-product (IV) is prepared and readily transformed to the C7-C15 segment of e