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ChemInform Abstract: A Facile Cross-Metathesis—Radical-Cyclization Approach to Monobenzannulated Spiroketals.

✍ Scribed by Yen-Cheng Liu; Jonathan Sperry; Dominea C. K. Rathwell; Margaret A. Brimble

Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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A Diastereoselective Radical Cyclization Approach to Pyroglutamates. -The 5-endo radical cyclization of pyruvic acid derived dehydroalanines (VI) possessing chiral ester auxiliaries is reported. The diastereoselectivity can be increased up to 6:1 by cyclization of the corresponding 8-phenylmenthyl