ChemInform Abstract: A Case of Competitive Demethylation by Boron Tribromide-Methyl Sulfide Complex. A New Route to Oxazoloquinolines.
β Scribed by C. BEVIERE; R. ROCHER; J. CHENAULT
- Book ID
- 101868730
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins. -Two equivalents of vinylthiiranes (I) are transformed in the presence of W(CO) 5 (MeCN) catalyst to dithiins (II) and butadiene in good yields. Complexes W(CO) 4 (PPhR 2 )(MeCN) (R