## Abstract The novel propellane 3 containing an electronβrich cyclohexadiene and an electronβdeficient diazadiene system in one and the same molecule reacts site selectively with the electronβrich alkynes 4 and 8 as well as with cyclooctyne (10) to yield the interestingly substituted novel 1,6βmet
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ChemInform Abstract: (4 + 2) Cycloaddition Reactions of a 4a,8a-Methanophthalazine with Electron-Rich Alkynes: A New Synthesis of Substituted 1,6-Methano(10) annulenes.
β Scribed by J. LAUE; G. SEITZ
- Book ID
- 112037567
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.