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ChemInform Abstract: (4 + 2) Cycloaddition Reactions of a 4a,8a-Methanophthalazine with Electron-Rich Alkynes: A New Synthesis of Substituted 1,6-Methano(10) annulenes.

✍ Scribed by J. LAUE; G. SEITZ


Book ID
112037567
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


[4 + 2] Cycloaddition Reactions of a 4a,
✍ Laue, JΓΆrg ;Seitz, Gunther πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 306 KB πŸ‘ 1 views

## Abstract The novel propellane 3 containing an electron‐rich cyclohexadiene and an electron‐deficient diazadiene system in one and the same molecule reacts site selectively with the electron‐rich alkynes 4 and 8 as well as with cyclooctyne (10) to yield the interestingly substituted novel 1,6‐met

Generation and [4+2] cycloaddition of 1,
✍ Shigeyasu Kuroda; Mitsunori Oda; Shengli Zuo; Kimiko Kanayama; Shaheen I.M Shah; πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 77 KB

A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.