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ChemInform Abstract: Synthesis and Reactions of New Ethynyl-Substituted 1,6-Methano(10) annulenes

✍ Scribed by A. BRYANT-FRIEDRICH; R. NEIDLEIN

Book ID
112031754
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Dedicated to Professor Mirhoel Hunack on the occasion of his 65th birthday (1 6.VII. 96) The treatment of bromo-substituted 1,6-methano[lO]annulenes with sodium thiolates in DMF provides easy access to alkylthio-and arylthio-substituted 1,6-methano[l0]annulenes (Schemes 2 4 ) . These compounds are