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ChemInform Abstract: Synthesis and (4 + 2) Cycloaddition Reactions of 4a,8a- Methanophthalazine, the First Propellane with an Electron-Rich and an Electron-Deficient 4π-Diene System.

✍ Scribed by J. LAUE; G. SEITZ; H. WASSMUTH


Book ID
112034394
Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
27
Category
Article
ISSN
0931-7597

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[4 + 2] Cycloaddition Reactions of a 4a,
✍ Laue, Jörg ;Seitz, Gunther 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 306 KB 👁 1 views

## Abstract The novel propellane 3 containing an electron‐rich cyclohexadiene and an electron‐deficient diazadiene system in one and the same molecule reacts site selectively with the electron‐rich alkynes 4 and 8 as well as with cyclooctyne (10) to yield the interestingly substituted novel 1,6‐met