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ChemInform Abstract: 1,5-Asymmetric Induction in Reactions between 4- and 5-Alkoxy-pent-2- enyl(tributyl)stannanes and Achiral 1-Alkoxycarbonylimines.

โœ Scribed by D. J. HALLETT; E. J. THOMAS


Book ID
112028856
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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1,5-Induction in reactions of 4-alkoxy-2
โœ Nicholas H Taylor; Eric J Thomas ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 759 KB

2-Trimethylsilylalk-2-enylstannanes undergo tin(IV) chloride promoted reactions with aldehydes to give homoallylic alcohols with retention of the 2-lrimethylsilyl group. 4-Alkoxy-2-trimethylsilylalk-2-enyl(tributyl)stannane 31 reacts with aldehydes under these conditions with excellent stereoselecti