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1,6-Asymmetric induction in reactions between 6-hydroxy-5-methylhex-2-enyl(tributyl)stannane and aldehydes promoted by tin(IV) bromide

โœ Scribed by Steve J. Stanway; Eric J. Thomas


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
205 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Remote asymmetric induction in reactions
โœ Christopher T. Brain; Eric J. Thomas ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 286 KB

Following observations on remote asymmetic induction using allylstannanes, 5-benzyloxy4 methylpent-2-enylsilanes are also found to react with aldebydes with modest levels of l,%induction after treatment with tin(IV) chloride. Transmetallation to give intermediite ally& hihalides may be involved.