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1,5-Asymmetric induction in reactions between 4- and 5-alkoxypent-2-enyl(tributyl)stannanes and achiral 1-alkoxycarbonylimines

โœ Scribed by David J Hallett; Eric J Thomas


Book ID
108036342
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
195 KB
Volume
6
Category
Article
ISSN
0957-4166

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1,5-Induction in reactions of 4-alkoxy-2
โœ Nicholas H Taylor; Eric J Thomas ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 759 KB

2-Trimethylsilylalk-2-enylstannanes undergo tin(IV) chloride promoted reactions with aldehydes to give homoallylic alcohols with retention of the 2-lrimethylsilyl group. 4-Alkoxy-2-trimethylsilylalk-2-enyl(tributyl)stannane 31 reacts with aldehydes under these conditions with excellent stereoselecti