Evidence IS gvcn that the y~clds ot photoculdatmn for free pyrenc amens (n-) and for xuons sssoclated %tth SOdlum cdtlons(n-Na+) m hquld THF and THP xe connected to the cffectlvc threshold values for the pnoto--ronlUtton of free and associated pyrenc anlons Our cxpermmcntal results mdlcate that the
Chemiluminescence in the oxidation of sodium anthracenide and pyrenide by a RuIIIcomplex
โ Scribed by R. G. Bulgakov; B. A. Tishin
- Book ID
- 105595880
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 160 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1573-9171
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## Abstract Two different mechanisms of inhibition of chemiluminescence in the oxidation of luminol by sodium hypochlorite were found. Most substances investigated in these experiments acted by scavenging NaOCI. This mechanism was independent of the concentration of hydrogen peroxide and the incuba
Hydrogen peroxide amplifies the chemiluminescence in the odixation of luminol by sodium hypochlorite. A linear relationship between concentration of hydrogen peroxide and light intensity was found in the concentration range 5 x 10-\*-7.5 x mol/l. At 7.5 x l o -' mol/l H,Oz the chemiluminescence is a