Chemiluminescence in the gas phase reaction between tetrakis (dimethylamino)ethylene and oxygen
β Scribed by Sidney Toby; Paul A. Astheimer; Frina S. Toby
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 648 KB
- Volume
- 67
- Category
- Article
- ISSN
- 1010-6030
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π SIMILAR VOLUMES
The kinetics of the reaction between ozone and allene (A) were studied in the range of 226 to 325Β°K in the gas phase. Initial O3 pressures varied from 0.01 to 0.7 torr and allene pressures varied from 0.05 to 6 torr. At the higher initial 0 3 pressures the most important product was 0 2 followed by
um atoms. Contact ion pairs are presumably also present in CH,CI, and CHCI, solvents since no sharp 19F NMR resonances were observed in freshly prepared solutions of 3. Concentrated solutions of 3 are only metastable at room temperature, however, their blue color disappearing after approximately one
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