Chemiluminescence in the gas-phase reactions of ozone with cyanoacetylene, carbon disulfide and thiophene
β Scribed by Sidney Toby; Frina S. Toby; Bruce A. Kaduk
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 226 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction between ozone and thiophene was studied from 30 to 125Β°C over a pressure range of 0.005-0.3 torr ozone and 0.1-1 torr thiophene. The most abundant product was 0 2 with smaller amounts of CO, and SOZ. The mass balance was 100% for oxygen and approached 100yo for sulfur a t the higher val
## Abstract The complex potential energy surface of the gasβphase reaction of HB(H)BH^β^ with CS~2~ to give three lowβlying products [B~2~H~3~S]^β^+CS, [BH~2~CS]^β^+HBS, and [BH~3~CS]+BS^β^, involving nine [B~2~H~3~CS~2~]^β^ isomers and 12 transition states, has been investigated at the CCSD(T)/6β3
Absolute rate constants for the gas phase reaction of OH radicals with pyrrole tk,) and thiophene ( k , ) have been measured over the temperature ranges 298-440 and 274-382 K, respectively, using the flash photolysis-resonance fluorescence technique. The rate constants obtained were independent of t