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Kinetic Relationships between Reactions in the Gas Phase and in Solution

✍ Scribed by Prof. Dr. H. Martin

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
634 KB
Volume
5
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

The kinetics of the gas-phase reaction b
The kinetics of the gas-phase reaction between ozone and alkenes
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The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti

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Comparison between solution-phase stability and gas-phase kinetic stability of oligodeoxynucleotide duplexes
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## Abstract The relative kinetic stabilities of different 16‐mer oligonucleotide duplexes were investigated by source collision‐induced dissociation (CID) in a heated capillary electrospray ion source. They were compared with the relative stabilities in solution obtained by thermal denaturation mon

Reaction between ozone and allene in the
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✍ Frina S. Toby; Sidney Toby πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 490 KB πŸ‘ 2 views

The kinetics of the reaction between ozone and allene (A) were studied in the range of 226 to 325Β°K in the gas phase. Initial O3 pressures varied from 0.01 to 0.7 torr and allene pressures varied from 0.05 to 6 torr. At the higher initial 0 3 pressures the most important product was 0 2 followed by

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The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M