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Chemical retro-cyclopropanation reactions in methanofullerenes: effect of the 18-crown-6 moiety

✍ Scribed by M Ángeles Herranz; José A Rivera; Robert J Alvarado; Nazario Martı́n; Carlo Thilgen; François Diederich; Luis Echegoyen

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
190 KB
Volume
1
Category
Article
ISSN
1472-7862

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✍ Florian Kraus; Tobias Hanauer; Nikolaus Korber 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB 👁 3 views

The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl