Chemical properties of the fulvene radical cation: a cycloaddition with 1,3-butadiene
β Scribed by Russell, David H.; Gross, M. L.
- Book ID
- 126330652
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 764 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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The 1,fbutadiene radical cation reacts with acrolein and methyl vinyl ketone to produce 'stable' adducts. The nature of the reaction and the structures of the adducts were investigated by collisional activation decomposition (CAD) combined with tandem mass spectrometry (MS/MS), and also by Fourier t
## Abstract The conversion of the cyclobutene cation radical to the 1,3βbutadiene cation radical has been studied using MINDO/3 and __ab initio__ SCF MO methods. Not only smooth electrocyclic but also stepwise, nonβelectrocyclic routes were considered. Both calculational methods agree that the pref
Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup
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