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Chemical oxidation and metabolism of N-methyl-N-formylhydrazine. Evidence for diazenium and radical intermediates

โœ Scribed by P.M. Gannett; C. Garrett; T. Lawson; B. Toth


Book ID
119160154
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
694 KB
Volume
29
Category
Article
ISSN
0278-6915

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โœ John P. Lorand; Russell W. Grant; Mrs.Patricia A. Samuel ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 100 KB

We wish to report direct evidence for a homolytic scission-recombination mechanism in the thermal eMeisenheimer" rearrangement' of the title compound, I, to the hydroxylamine, II (equation I). This mechanism W&B apparently first proposed by Schgllkopf,3 who adduced threefold