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Evidence for radical mechanism and a cage effect in the thermal rearrangement of N-benzyl-N-methylaniline N-oxide

✍ Scribed by John P. Lorand; Russell W. Grant; Mrs.Patricia A. Samuel

Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 100 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88622-6

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✦ Synopsis

We wish to report direct evidence for a homolytic scission-recombination mechanism in the thermal eMeisenheimer" rearrangement' of the title compound, I, to the hydroxylamine, II (equation I). This mechanism W&B apparently first proposed by Schgllkopf,3 who adduced threefold

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