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Chemical Bonding in Si 52- and NaSi 5- via Photoelectron Spectroscopy and ab Initio Calculations †

✍ Scribed by Zubarev, Dmitry Yu.; Boldyrev, Alexander I.; Li, Xi; Cui, Li-Feng; Wang, Lai-Sheng


Book ID
121381408
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
399 KB
Volume
109
Category
Article
ISSN
1089-5639

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To establish whether through-bond (TB) orbital interactions occur between the functional groups and the hydrocarbon skeleton in a series of end-functionalized oligo(cyclohexylidenes) 1-12, their He I photoelectron (PE) spectra were measured and analyzed. Vertical ionization energies, I vj , of the h

ChemInform Abstract: Through-Bond Orbita
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v