Electronic Structure and Chemical Bonding in MOn- and MOn Clusters (M: Mo, W; n = 3—5): A Photoelectron Spectroscopy and ab initio Study.

Heterometallic Nitrido-Carbonyl Clusters

Heterometallic Nitrido-Carbonyl Clusters − Synthesis and Characterization of [Fe5MN(CO)14(C5H5)]2−, [Fe3M3N(CO)18]3− (M = Mo, W) and [HFe5MoN(CO)16]2− and Solid-State Structures of [Fe5MoN(CO)14(C5H5)]2−, [Fe5WN(CO)14(C5H5)]2−, and [Fe3Mo3N(CO)18]3−

✍ Roberto Della Pergola; Massimiliano Branchini; Alessandro Fumagalli; Luigi Garla 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 326 KB 👁 2 views

The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit