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ChemInform Abstract: Through-Bond Orbital Coupling in End-Functionalized Bicyclohexylidenes — Photoelectron Spectroscopy and ab initio SCF—MO Calculations.

✍ Scribed by Albert W. Marsman; Remco W. A. Havenith; Sabine Bethke; Leonardus W. Jenneskens; Rolf Gleiter; Joop H. van Lenthe


Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Abstract

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Through-Bond Orbital Coupling in End-Fun
✍ Albert W. Marsman; Remco W. A. Havenith; Sabine Bethke; Leonardus W. Jenneskens; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 601 KB

To establish whether through-bond (TB) orbital interactions occur between the functional groups and the hydrocarbon skeleton in a series of end-functionalized oligo(cyclohexylidenes) 1-12, their He I photoelectron (PE) spectra were measured and analyzed. Vertical ionization energies, I vj , of the h