Charge-transfer satellites in the x-ray photoelectron spectra of 3d° and 4d° metal oxides
✍ Scribed by M S Hegde
- Book ID
- 112896873
- Publisher
- Springer-Verlag
- Year
- 1980
- Tongue
- English
- Weight
- 183 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0250-4707
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📜 SIMILAR VOLUMES
Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This
Charge-transfer satellites due to eg + eg\* and alg -+ aTg transitions have been observed for the first time next to the &and core level peaks in the X-ray photoelectron spectra of metal chlorides and sulphides. These transitions are also seen neat to the metal core levels in the case of the chlorid