✦ LIBER ✦

Charge-transfer satellites next to ligand core levels in the x-ray photoelectron spectra of metal chlorides and sulphides

✍ Scribed by P.Vishnu Kamath; D.D. Sarma; C.N.R. Rao

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 436 KB
Volume: 101
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87012-2

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✦ Synopsis

Charge-transfer satellites due to eg + eg* and alg -+ aTg transitions have been observed for the first time next to the &and core level peaks in the X-ray photoelectron spectra of metal chlorides and sulphides. These transitions are also seen neat to the metal core levels in the case of the chlorides_ Observation of these satellites, specially in the case of sulphides, underscores the crucial role of metal-ligand overlap in determining the intensity of charge-transfer satellites.