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Characterization of triplet states of axially symmetric benzenes using the zeeman effect

✍ Scribed by R.M Hochstrasser; J.E Wessel; J.D Whiteman; A.H Zewail

Book ID
103013759
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
368 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

By m&k of low t&perature spec&scopy of &Ie cry& of sym-tihloiobenzene (TCB) and sym-triiromobenzene (TBB) we have detexninud that the principal Her&erg-Telkorigins in the So + Tt tksition correspond to out-of-planeviirations The &&led active modes for TCB are: 205 cm-' (e"); 144 cm-' (a;) fkom phosphores &xx; 119 Cm-' (e" or 3:). fkom absorption. For TBB the assigned modes are: 203 cm-' (e") from phosphoreskence; -.

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