✦ LIBER ✦

Assignment of the lowest triplet state of benzene using phosphorescence-microwave double resonance (PMDR) techniques

✍ Scribed by A.A. Gwaiz; M.A. El-Sayed; D.S. Tinti

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 322 KB
Volume: 9
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80266-x

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✦ Synopsis

Phosphorescence-microwave double resonance (PMDR) techniques are wed and the zero-field (zf) origin of the 0,O band of the phosphorescence of benzene-& in benzene-& a.t 1.6% is determined to be the TY level. This is cuns;tent with a 3B1u assignment for a distorted D2h benzene in its triplet state and coatraclicts a recently suggested 3Ba assignment.