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Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane

✍ Scribed by Eduard; A. Duban; Konstantin; P. Bryliakov; Evgenii; P. Talsi

Book ID
111730527
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
161 KB
Volume
15
Category
Article
ISSN
0959-9436

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## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole

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Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.032 wR factor = 0.034 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.