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Characterization and Photochemistry of the Gallium and Indium Subhydrides Ga2H2 and In2H2

✍ Scribed by Hans-Jörg Himmel; Laurent Manceron; Anthony J. Downs; Pluton Pullumbi


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
104 KB
Volume
41
Category
Article
ISSN
0044-8249

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The first 1,2-azaphosphindoles 14a,b, 15a,b were obtained in a straightforward manner upon heating diphenylzirconocene in the presence of a cyanophosphane, which afforded azazirconacyclopentenes 11a,b which can be reacted with various dichlorophosphanes. The use of the tetrachlorodiphosphane Cl 2 P(