2H-1,2-Azaphosphindoles – Synthesis and
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Victorio Cadierno; Bruno Donnadieu; Alain Igau; Jean-Pierre Majoral
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Article
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2000
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John Wiley and Sons
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English
⚖ 260 KB
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The first 1,2-azaphosphindoles 14a,b, 15a,b were obtained in a straightforward manner upon heating diphenylzirconocene in the presence of a cyanophosphane, which afforded azazirconacyclopentenes 11a,b which can be reacted with various dichlorophosphanes. The use of the tetrachlorodiphosphane Cl 2 P(