The gas-phase acidities of the most stable conformations of nine sulfur oxo acids were determined by ab initio MO calculations at the CBS-Q, G2(MP2), and G2 levels of theory. The most accurate G2 results are as follows (∆G°2 98 of the deprotonation reaction in kJ mol -1 ): H-S-O-H 1468, H-S-O-H 1449
Gas-Phase Structures and Acidities of the Sulfur Oxoacids H2SnO6 (n = 2−4) and H2S2O7
✍ Scribed by André H. Otto; Ralf Steudel
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 473 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
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