Chain Reaction for Isomerization from trans(Cl) to cis(Cl)-Ru(bpy)(CO)2Cl2 (bpy = 2,2′-Bipyridine) Induced by NaBH4
✍ Scribed by Yusuke Kuramochi; Yasuhiro Ito; Hitoshi Ishida
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 289 KB
- Volume
- 2012
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Salt effects on the oxidation of the iron(II) complexes Fe(CN)~4~(bpy)^2−^, __cis__‐(CN)~2~(bpy)~2~ and Fe(bpy)~3~^2+^ by S~2~O~8~^2−^ as well as on the reaction Fe^2+^ + Co(NH~3~)~5~Cl^2+^ have been studied in concentrated electrolyte solutions at 298.2 K. We have gone from anion–anion
Aqueous hydrogen halides HX (X = Cl, Br, I) are shown to containing derivatives, but the only stable isomer containing iodine was trans(I)-Ru(dmbpy)(CO) 2 I 2 . The failure to obtain be excellent halogen sources for the synthesis of a series of halogen-containing ruthenium mono(2,2Ј-bipyridine) car-